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Proton
Gist
Proton is an elementary particle that is identical with the nucleus of the hydrogen atom, that along with the neutron is a constituent of all other atomic nuclei, that carries a positive charge numerically equal to the charge of an electron, and that has a mass of 1.673 × {10}^{-27} kilogram.
Summary
A Proton is one of the three basic subatomic particles—along with neutrons and electrons—that make up atoms, the basic building blocks of all matter and chemistry. It is the positively charged particle that, together with the electrically neutral particles called neutrons, make up the nucleus of an atom. (The nucleus of the ordinary hydrogen atom is an exception; it contains one proton but no neutrons.) Neutrons are slightly heavier than protons in mass, but the proton is 1,836 times heavier than the mass of an electron, which is the lightest charged particle in nature. The proton’s positive charge is equal and opposite to the negative charge on an electron, meaning a neutral atom has an equal number of protons and electrons.
More than 90 types of atoms exist in nature, and each kind of atom forms a different chemical element. Every nucleus of a given chemical element has the same number of protons, and this quantity of protons defines the atomic number of the element and determines the element’s position in the periodic table.
The discovery of the proton dates to the earliest investigations of atomic structure. While studying streams of ionized gaseous atoms and molecules from which electrons had been stripped, Wilhelm Wien (1898) and J.J. Thomson (1910) identified a positive particle equal in mass to the hydrogen atom. Ernest Rutherford showed (1919) that nitrogen under alpha-particle bombardment ejects what appear to be hydrogen nuclei. By 1920 he had accepted the hydrogen nucleus as an elementary particle, naming it proton.
High-energy particle-physics studies in the late 20th century refined the structural understanding of the nature of the proton within the group of subatomic particles. Protons and neutrons have been shown to be made up of smaller particles and are classified as baryons—particles composed of three elementary units of matter known as quarks.
Protons from ionized hydrogen are given high velocities in particle accelerators and are commonly used as projectiles to produce and study nuclear reactions. Protons are the chief constituent of primary cosmic rays and are among the products of some types of artificial nuclear reactions.
Details
A proton is a stable subatomic particle, symbol p + with a positive electric charge of +1 e (elementary charge). Its mass is slightly less than that of a neutron and 1,836 times the mass of an electron (the proton-to-electron mass ratio). Protons and neutrons, each with masses of approximately one atomic mass unit, are jointly referred to as "nucleons" (particles present in atomic nuclei).
One or more protons are present in the nucleus of every atom. They provide the attractive electrostatic central force that binds the atomic electrons. The number of protons in the nucleus is the defining property of an element, and is referred to as the atomic number (represented by the symbol Z). Since each element has a unique number of protons, each element has its own unique atomic number, which determines the number of atomic electrons and consequently the chemical characteristics of the element.
The word proton is Greek for "first", and this name was given to the hydrogen nucleus by Ernest Rutherford in 1920. In previous years, Rutherford had discovered that the hydrogen nucleus (known to be the lightest nucleus) could be extracted from the nuclei of nitrogen by atomic collisions. Protons were therefore a candidate to be a fundamental or elementary particle, and hence a building block of nitrogen and all other heavier atomic nuclei.
Although protons were originally considered to be elementary particles, in the modern Standard Model of particle physics, protons are now known to be composite particles, containing three valence quarks, and together with neutrons are now classified as hadrons. Protons are composed of two up quarks of charge +2/3 e and one down quark of charge −1/3 e. The rest masses of quarks contribute only about 1% of a proton's mass. The remainder of a proton's mass is due to quantum chromodynamics binding energy, which includes the kinetic energy of the quarks and the energy of the gluon fields that bind the quarks together. Because protons are not fundamental particles, they possess a measurable size; the root mean square charge radius of a proton is about 0.84–0.87 fm (1 fm = {10}^{-15} m). In 2019, two different studies, using different techniques, found this radius to be 0.833 fm, with an uncertainty of ±0.010 fm.
Free protons occur occasionally on Earth: thunderstorms can produce protons with energies of up to several tens of MeV. At sufficiently low temperatures and kinetic energies, free protons will bind to electrons. However, the character of such bound protons does not change, and they remain protons. A fast proton moving through matter will slow by interactions with electrons and nuclei, until it is captured by the electron cloud of an atom. The result is a diatomic or polyatomic ion containing hydrogen. In a vacuum, when free electrons are present, a sufficiently slow proton may pick up a single free electron, becoming a neutral hydrogen atom, which is chemically a free radical. Such "free hydrogen atoms" tend to react chemically with many other types of atoms at sufficiently low energies. When free hydrogen atoms react with each other, they form neutral hydrogen molecules (H2), which are the most common molecular component of molecular clouds in interstellar space.
Free protons are routinely used for accelerators for proton therapy or various particle physics experiments, with the most powerful example being the Large Hadron Collider.
Description
Protons are spin -1/2 fermions and are composed of three valence quarks, making them baryons (a sub-type of hadrons). The two up quarks and one down quark of a proton are held together by the strong force, mediated by gluons. A modern perspective has a proton composed of the valence quarks (up, up, down), the gluons, and transitory pairs of sea quarks. Protons have a positive charge distribution, which decays approximately exponentially, with a root mean square charge radius of about 0.8 fm.
Protons and neutrons are both nucleons, which may be bound together by the nuclear force to form atomic nuclei. The nucleus of the most common isotope of the hydrogen atom (with the chemical symbol "H") is a lone proton. The nuclei of the heavy hydrogen isotopes deuterium and tritium contain one proton bound to one and two neutrons, respectively. All other types of atomic nuclei are composed of two or more protons and various numbers of neutrons.
History
The concept of a hydrogen-like particle as a constituent of other atoms was developed over a long period. As early as 1815, William Prout proposed that all atoms are composed of hydrogen atoms (which he called "protyles"), based on a simplistic interpretation of early values of atomic weights (see Prout's hypothesis), which was disproved when more accurate values were measured.
In 1886, Eugen Goldstein discovered canal rays (also known as anode rays) and showed that they were positively charged particles (ions) produced from gases. However, since particles from different gases had different values of charge-to-mass ratio (q/m), they could not be identified with a single particle, unlike the negative electrons discovered by J. J. Thomson. Wilhelm Wien in 1898 identified the hydrogen ion as the particle with the highest charge-to-mass ratio in ionized gases.
Following the discovery of the atomic nucleus by Ernest Rutherford in 1911, Antonius van den Broek proposed that the place of each element in the periodic table (its atomic number) is equal to its nuclear charge. This was confirmed experimentally by Henry Moseley in 1913 using X-ray spectra.
In 1917, experiments (reported in 1919 and 1925), Rutherford proved that the hydrogen nucleus is present in other nuclei, a result usually described as the discovery of protons. These experiments began after Rutherford observed that when alpha particles would strike air, Rutherford could detect scintillation on a zinc sulfide screen produced at a distance well beyond the distance of alpha-particle range of travel but instead corresponding to the range of travel of hydrogen atoms (protons). After experimentation, Rutherford traced the reaction to the nitrogen in air and found that when alpha particles were introduced into pure nitrogen gas, the effect was larger. In 1919, Rutherford assumed that the alpha particle merely knocked a proton out of nitrogen, turning it into carbon. After observing Blackett's cloud chamber images in 1925, Rutherford realized that the alpha particle was absorbed because if the alpha particle was not absorbed, then the alpha particle must knock a proton off of nitrogen creating 3 charged particles (a negatively charged carbon, a proton, and an alpha particle). It can be shown that it will create three tracks in the cloud chamber, but instead we observe only 2 tracks in the cloud chamber. After capture of the alpha particle, a hydrogen nucleus is ejected, so that heavy oxygen, not carbon, is the result – i.e., the atomic number Z of the nucleus is increased rather than reduced.
Depending on one's perspective, either 1919 (when it was seen experimentally as derived from another source than hydrogen) or 1920 (when it was recognized and proposed as an elementary particle) may be regarded as the moment when the proton was 'discovered'.
Rutherford knew hydrogen to be the simplest and lightest element and was influenced by Prout's hypothesis that hydrogen was the building block of all elements. Discovery that the hydrogen nucleus is present in other nuclei as an elementary particle led Rutherford to give the hydrogen nucleus H+ a special name as a particle, since he suspected that hydrogen, the lightest element, contained only one of these particles. He named this new fundamental building block of the nucleus the proton, after the neuter singular of the Greek word for "first". However, Rutherford also had in mind the word protyle as used by Prout. Rutherford spoke at the British Association for the Advancement of Science at its Cardiff meeting beginning 24 August 1920. At the meeting, he was asked by Oliver Lodge for a new name for the positive hydrogen nucleus to avoid confusion with the neutral hydrogen atom. He initially suggested both proton and prouton (after Prout). Rutherford later reported that the meeting had accepted his suggestion that the hydrogen nucleus be named the "proton", following Prout's word "protyle". The first use of the word "proton" in the scientific literature appeared in 1920.
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