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Chlorophyll
Gist
Chlorophyll is a pigment that gives plants their green color, and it helps plants create their own food through photosynthesis.
Chlorophyll is a pigment found in the chloroplasts of cells. During photosynthesis, chlorophyll absorbs light from the sun and turns it into chemical energy the plant can use as food.
Summary
Chlorophyll is a pigment that gives plants their green color, and it helps plants create their own food through photosynthesis.
Green plants have the ability to make their own food. They do this through a process called photosynthesis, which uses a green pigment called chlorophyll. A pigment is a molecule that has a particular color and can absorb light at different wavelengths, depending on the color. There are many different types of pigments in nature, but chlorophyll is unique in its ability to enable plants to absorb the energy they need to build tissues.
Chlorophyll is located in a plant’s chloroplasts, which are tiny structures in a plant’s cells. This is where photosynthesis takes place. Phytoplankton, the microscopic floating plants that form the basis of the entire marine food web, contain chlorophyll, which is why high phytoplankton concentrations can make water look green.
Chlorophyll’s job in a plant is to absorb light—usually sunlight. The energy absorbed from light is transferred to two kinds of energy-storing molecules. Through photosynthesis, the plant uses the stored energy to convert carbon dioxide (absorbed from the air) and water into glucose, a type of sugar. Plants use glucose together with nutrients taken from the soil to make new leaves and other plant parts. The process of photosynthesis produces oxygen, which is released by the plant into the air.
Chlorophyll gives plants their green color because it does not absorb the green wavelengths of white light. That particular light wavelength is reflected from the plant, so it appears green.
Plants that use photosynthesis to make their own food are called autotrophs. Animals that eat plants or other animals are called heterotrophs. Because food webs in every type of ecosystem, from terrestrial to marine, begin with photosynthesis, chlorophyll can be considered a foundation for all life on Earth.
Details
Chlorophyll is any of several related green pigments found in cyanobacteria and in the chloroplasts of algae and plants. Its name is derived from the Greek words (khloros, "pale green") and (phyllon, "leaf"). Chlorophyll allows plants to absorb energy from light. Those pigments are involved in oxygenic photosynthesis, as opposed to bacteriochlorophylls, related molecules found only in bacteria and involved in anoxygenic photosynthesis.
Chlorophylls absorb light most strongly in the blue portion of the electromagnetic spectrum as well as the red portion. Conversely, it is a poor absorber of green and near-green portions of the spectrum. Hence chlorophyll-containing tissues appear green because green light, diffusively reflected by structures like cell walls, is less absorbed. Two types of chlorophyll exist in the photosystems of green plants: chlorophyll a and b.
History
Chlorophyll was first isolated and named by Joseph Bienaimé Caventou and Pierre Joseph Pelletier in 1817. The presence of magnesium in chlorophyll was discovered in 1906, and was the first detection of that element in living tissue.
After initial work done by German chemist Richard Willstätter spanning from 1905 to 1915, the general structure of chlorophyll a was elucidated by Hans Fischer in 1940. By 1960, when most of the stereochemistry of chlorophyll a was known, Robert Burns Woodward published a total synthesis of the molecule. In 1967, the last remaining stereochemical elucidation was completed by Ian Fleming, and in 1990 Woodward and co-authors published an updated synthesis. Chlorophyll f was announced to be present in cyanobacteria and other oxygenic microorganisms that form stromatolites in 2010; a molecular formula of C55H70O6N4Mg and a structure of (2-formyl)-chlorophyll a were deduced based on NMR, optical and mass spectra.
Photosynthesis
Chlorophyll is vital for photosynthesis, which allows plants to absorb energy from light.
Chlorophyll molecules are arranged in and around photosystems that are embedded in the thylakoid membranes of chloroplasts. In these complexes, chlorophyll serves three functions:
* The function of the vast majority of chlorophyll (up to several hundred molecules per photosystem) is to absorb light.
* Having done so, these same centers execute their second function: The transfer of that energy by resonance energy transfer to a specific chlorophyll pair in the reaction center of the photosystems.
* This specific pair performs the final function of chlorophylls: Charge separation, which produces the unbound protons (H+) and electrons (e−) that separately propel biosynthesis.
The two currently accepted photosystem units are photosystem I and photosystem II, which have their own distinct reaction centres, named P700 and P680, respectively. These centres are named after the wavelength (in nanometers) of their red-peak absorption maximum. The identity, function and spectral properties of the types of chlorophyll in each photosystem are distinct and determined by each other and the protein structure surrounding them.
The function of the reaction center of chlorophyll is to absorb light energy and transfer it to other parts of the photosystem. The absorbed energy of the photon is transferred to an electron in a process called charge separation. The removal of the electron from the chlorophyll is an oxidation reaction. The chlorophyll donates the high energy electron to a series of molecular intermediates called an electron transport chain. The charged reaction center of chlorophyll (P680+) is then reduced back to its ground state by accepting an electron stripped from water. The electron that reduces P680+ ultimately comes from the oxidation of water into O2 and H+ through several intermediates. This reaction is how photosynthetic organisms such as plants produce O2 gas, and is the source for practically all the O2 in Earth's atmosphere. Photosystem I typically works in series with Photosystem II; thus the P700+ of Photosystem I is usually reduced as it accepts the electron, via many intermediates in the thylakoid membrane, by electrons coming, ultimately, from Photosystem II. Electron transfer reactions in the thylakoid membranes are complex, however, and the source of electrons used to reduce P700+ can vary.
The electron flow produced by the reaction center chlorophyll pigments is used to pump H+ ions across the thylakoid membrane, setting up a proton-motive force a chemiosmotic potential used mainly in the production of ATP (stored chemical energy) or to reduce NADP+ to NADPH. NADPH is a universal agent used to reduce CO2 into sugars as well as other biosynthetic reactions.
Reaction center chlorophyll–protein complexes are capable of directly absorbing light and performing charge separation events without the assistance of other chlorophyll pigments, but the probability of that happening under a given light intensity is small. Thus, the other chlorophylls in the photosystem and antenna pigment proteins all cooperatively absorb and funnel light energy to the reaction center. Besides chlorophyll a, there are other pigments, called accessory pigments, which occur in these pigment–protein antenna complexes.
Additional Information
Chlorophyll is any member of the most important class of pigments involved in photosynthesis, the process by which light energy is converted to chemical energy through the synthesis of organic compounds. Chlorophyll is found in virtually all photosynthetic organisms, including green plants, cyanobacteria, and algae. It absorbs energy from light; this energy is then used to convert carbon dioxide to carbohydrates.
Chlorophyll occurs in several distinct forms: chlorophylls a and b are the major types found in higher plants and green algae; chlorophylls c and d are found, often with a, in different algae; chlorophyll e is a rare type found in some golden algae; and bacterio-chlorophyll occurs in certain bacteria. In green plants chlorophyll occurs in membranous disklike units (thylakoids) in organelles called chloroplasts.
The chlorophyll molecule consists of a central magnesium atom surrounded by a nitrogen-containing structure called a porphyrin ring; attached to the ring is a long carbon–hydrogen side chain, known as a phytol chain. Variations are due to minor modifications of certain side groups. Chlorophyll is remarkably similar in structure to hemoglobin, the oxygen-carrying pigment found in the red blood cells of mammals and other vertebrates.
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