Math Is Fun Forum

2306) Graphite

Gist

Graphite is a type of crystal carbon and a half-metal along with being one of the renowned carbon allotropes. Under the conditions that are ideal, it would be one of the most stable forms of carbon available. To define the standard state of heat for making compounds of carbons.

Graphite is used in pencils, lubricants, crucibles, foundry facings, polishes, brushes for electric motors, and cores of nuclear reactors.

Summary

Graphite is a mineral consisting of carbon. Graphite has a greasy feel and leaves a black mark, thus the name from the Greek verb graphein, “to write.”

Graphite has a layered structure that consists of rings of six carbon atoms arranged in widely spaced horizontal sheets. Graphite thus crystallizes in the hexagonal system, in contrast to diamond, another form of carbon, that crystallizes in the octahedral or tetrahedral system. Such pairs of differing forms of the same element usually are rather similar in their physical properties, but not so in this case. Graphite is dark gray to black, opaque, and very soft (with a Mohs scale hardness of 1.5), while diamond may be colorless and transparent and is the hardest naturally occurring substance (with a Mohs scale hardness of 10). Graphite is very soft because the individual layers of carbon atoms are not as tightly bound together as the atoms within the layer. It is an excellent conductor of heat and electricity.

Graphite is formed by the metamorphosis of sediments containing carbonaceous material, by the reaction of carbon compounds with hydrothermal solutions or magmatic fluids, or possibly by the crystallization of magmatic carbon. It occurs as isolated scales, large masses, or veins in older crystalline rocks, gneiss, schist, quartzite, and marble and also in granites, pegmatites, and carbonaceous clay slates. Small isometric crystals of graphitic carbon (possibly pseudomorphs after diamond) found in meteoritic iron are called cliftonite.

Naturally occurring graphite is classified into three types: amorphous, flake, and vein. Amorphous is the most common kind and is formed by metamorphism under low pressures and temperatures. It is found in coal and shale and has the lowest carbon content, typically 70 to 90 percent, of the three types. Flake graphite appears in flat layers and is formed by metamorphism under high pressures and temperatures. It is the most commonly used type and has a carbon content between 85 and 98 percent. Vein graphite is the rarest form and is likely formed when carbon compounds react with hydrothermal solutions or magmatic fluids. Vein graphite can have a purity greater than 99 percent and is commercially mined only in Sri Lanka.

Graphite was first synthesized accidentally by Edward G. Acheson while he was performing high-temperature experiments on carborundum. He found that at about 4,150 °C (7,500 °F) the silicon in the carborundum vaporized, leaving the carbon behind in graphitic form. Acheson was granted a patent for graphite manufacture in 1896, and commercial production started in 1897. Since 1918 petroleum coke, small and imperfect graphite crystals surrounded by organic compounds, has been the major raw material in the production of 99 to 99.5 percent pure graphite.

Graphite is used in pencils, lubricants, crucibles, foundry facings, polishes, brushes for electric motors, and cores of nuclear reactors. Its high thermal and electrical conductivity make it a key part of steelmaking, where it is used as electrodes in electric arc furnaces. In the early 21st century, global demand for graphite has increased because of its use as the anode in lithium-ion batteries for electric vehicles. About 75 percent of graphite is mined in China, with significant amounts mined in Madagascar, Mozambique, and Brazil.

Details

Graphite is a crystalline allotrope (form) of the element carbon. It consists of many stacked layers of graphene typically in the excess of hundred(s) of layers. Graphite occurs naturally and is the most stable form of carbon under standard conditions. Synthetic and natural graphite are consumed on a large scale (1.3 million metric tons per year in 2022) for uses in many critical industries including refractories (50%), lithium-ion batteries (18%), foundries (10%), lubricants (5%), among others (17%). Under extremely high pressures and extremely high temperatures it converts to diamond. It is a good conductor of both heat and electricity

Types and varieties:

Natural graphite

Graphite occurs naturally in ores that can be classified into one of two categories either amorphous (microcrystalline) or crystalline (flake or lump/chip) which is determined by the ore morphology, crystallinity, and grain size.  All naturally occurring graphite deposits are formed from the metamorphism of carbonaceous sedimentary rocks, and the ore type is due to its geologic setting. Coal that has been thermally metamorphosed is the typical source of amorphous graphite. Crystalline flake graphite is mined from carbonaceous metamorphic rocks, while lump or chip graphite is mined from veins which occur in high-grade metamorphic regions. There are serious negative environmental impacts to graphite mining.

Synthetic graphite

Synthetic graphite is graphite of high purity produced by thermal graphitization at temperatures in excess of 2,100 °C from hydrocarbon materials most commonly by a process known as the Acheson process. The high temperatures are maintained for weeks, and are required not only to form the graphite from the precursor carbons but to also vaporize any impurities that may be present, including hydrogen, nitrogen, sulfur, organics, and metals. This is why synthetic graphite is highly pure in excess of 99.9% C purity, but typically has lower density, conductivity and a higher porosity than its natural equivalent. Synthetic graphite can also be formed into very large flakes (cm) while maintaining its high purity unlike almost all sources of natural graphite. Synthetic graphite has also been known to be formed by other methods including by chemical vapor deposition from hydrocarbons at temperatures above 2,500 K (2,230 °C), by decomposition of thermally unstable carbides or by crystallizing from metal melts supersaturated with carbon.

Biographite

Biographite is a commercial product proposal for reducing the carbon footprint of lithium iron phosphate (LFP) batteries. It is produced from forestry waste and similar byproducts by a company in New Zealand using a novel process called thermo-catalytic graphitisation which project is supported by grants from interested parties including a forestry company in Finland and a battery maker in Hong Kong.

Natural graphite:

Occurrence

Graphite occurs in metamorphic rocks as a result of the reduction of sedimentary carbon compounds during metamorphism. It also occurs in igneous rocks and in meteorites. Minerals associated with graphite include quartz, calcite, micas and tourmaline. The principal export sources of mined graphite are in order of tonnage: China, Mexico, Canada, Brazil, and Madagascar. Significant unexploited graphite resources also exists in Colombia's Cordillera Central in the form of graphite-bearing schists.

In meteorites, graphite occurs with troilite and silicate minerals. Small graphitic crystals in meteoritic iron are called cliftonite. Some microscopic grains have distinctive isotopic compositions, indicating that they were formed before the Solar System. They are one of about 12 known types of minerals that predate the Solar System and have also been detected in molecular clouds. These minerals were formed in the ejecta when supernovae exploded or low to intermediate-sized stars expelled their outer envelopes late in their lives. Graphite may be the second or third oldest mineral in the Universe.

Structure

Graphite consists of sheets of trigonal planar carbon. The individual layers are called graphene. In each layer, each carbon atom is bonded to three other atoms forming a continuous layer of sp2 bonded carbon hexagons, like a honeycomb lattice with a bond length of 0.142 nm, and the distance between planes is 0.335 nm. Bonding between layers is relatively weak van der Waals bonds, which allows the graphene-like layers to be easily separated and to glide past each other. Electrical conductivity perpendicular to the layers is consequently about 1000 times lower.

There are two allotropic forms called alpha (hexagonal) and beta (rhombohedral), differing in terms of the stacking of the graphene layers: stacking in alpha graphite is ABA, as opposed to ABC stacking in the energetically less stable beta graphite. Rhombohedral graphite cannot occur in pure form. Natural graphite, or commercial natural graphite, contains 5 to 15% rhombohedral graphite and this may be due to intensive milling. The alpha form can be converted to the beta form through shear forces, and the beta form reverts to the alpha form when it is heated to 1300 °C for four hours.

Thermodynamics

The equilibrium pressure and temperature conditions for a transition between graphite and diamond is well established theoretically and experimentally. The pressure changes linearly between 1.7 GPa at 0 K and 12 GPa at 5000 K (the diamond/graphite/liquid triple point). However, the phases have a wide region about this line where they can coexist. At normal temperature and pressure, 20 °C (293 K) and 1 standard atmosphere (0.10 MPa), the stable phase of carbon is graphite, but diamond is metastable and its rate of conversion to graphite is negligible. However, at temperatures above about 4500 K, diamond rapidly converts to graphite. Rapid conversion of graphite to diamond requires pressures well above the equilibrium line: at 2000 K, a pressure of 35 GPa is needed.

Other properties

The acoustic and thermal properties of graphite are highly anisotropic, since phonons propagate quickly along the tightly bound planes, but are slower to travel from one plane to another. Graphite's high thermal stability and electrical and thermal conductivity facilitate its widespread use as electrodes and refractories in high temperature material processing applications. However, in oxygen-containing atmospheres graphite readily oxidizes to form carbon dioxide at temperatures of 700 °C and above.

Graphite is an electrical conductor, hence useful in such applications as arc lamp electrodes. It can conduct electricity due to the vast electron delocalization within the carbon layers (a phenomenon called aromaticity). These valence electrons are free to move, so are able to conduct electricity. However, the electricity is primarily conducted within the plane of the layers. The conductive properties of powdered graphite allow its use as pressure sensor in carbon microphones.

Graphite and graphite powder are valued in industrial applications for their self-lubricating and dry lubricating properties. However, the use of graphite is limited by its tendency to facilitate pitting corrosion in some stainless steel, and to promote galvanic corrosion between dissimilar metals (due to its electrical conductivity). It is also corrosive to aluminium in the presence of moisture. For this reason, the US Air Force banned its use as a lubricant in aluminium aircraft, and discouraged its use in aluminium-containing automatic weapons. Even graphite pencil marks on aluminium parts may facilitate corrosion. Another high-temperature lubricant, hexagonal boron nitride, has the same molecular structure as graphite. It is sometimes called white graphite, due to its similar properties.

When a large number of crystallographic defects bind these planes together, graphite loses its lubrication properties and becomes what is known as pyrolytic graphite. It is also highly anisotropic, and diamagnetic, thus it will float in mid-air above a strong magnet. (If it is made in a fluidized bed at 1000–1300 °C then it is isotropic turbostratic, and is used in blood-contacting devices like mechanical heart valves and is called pyrolytic carbon, and is not diamagnetic. Pyrolytic graphite and pyrolytic carbon are often confused but are very different materials.)

Natural and crystalline graphites are not often used in pure form as structural materials, due to their shear-planes, brittleness, and inconsistent mechanical properties.

Additional Information

Graphite is a mineral composed of stacked sheets of carbon atoms with a hexagonal crystal structure. It is the most stable form of pure carbon under standard conditions. Graphite is very soft, has a low specific gravity, is relatively non-reactive, and has high electrical and thermal conductivity.

Graphite occurs naturally in igneous and metamorphic rocks, where high temperatures and pressures compress carbon into graphite. Graphite can also be created synthetically by heating materials with high carbon content (e.g. petroleum coke or coal-tar pitch). The carbon-rich material is heated to 2500 to 3000 degrees Celsius, which is hot enough to "purify" the material of contaminants, allowing the carbon to form its hexagonal sheets.

Graphite is extremely soft and breaks into thin flexible flakes that easily slide over one another, resulting in a greasy feel. Due to this, graphite is a good "dry" lubricant and can be used in applications where wet lubricants (like lubricating oil) cannot.

Carbon has several other allotropes, or forms, that occur naturally, each with their own crystal structure. One form is graphene, which is a single layer of carbon atoms in a hexagonal pattern. Another well-known allotrope of carbon, are diamonds. Although also composed of pure carbon, diamonds are almost entirely different in their physical properties.

Uses

Graphite is used in a number of applications that require high temperatures and need a material that will not melt or disintegrate. Graphite is used to make the crucibles for the steel industry. Graphite is also used as a neutron moderator in certain nuclear reactors, like the Soviet RBMK, due to its ability to slow down fast-moving neutrons.

Other common uses of graphite include:

* Pencil lead
* Lubricant
* Electrodes in batteries
* Brake linings for heavy vehicles.

Hi,

#2684. What does the medical term Choroidal nevus mean?

Hi,

#9338.

2305) Earphones / Headphones

Gist

Headphones are also known as earphones or, colloquially, cans. Circumaural (around the ear) and supra-aural (over the ear) headphones use a band over the top of the head to hold the drivers in place. Another type, known as earbuds or earpieces, consists of individual units that plug into the user's ear canal.

They are electroacoustic transducers, which convert an electrical signal to a corresponding sound. Headphones let a single user listen to an audio source privately, in contrast to a loudspeaker, which emits sound into the open air for anyone nearby to hear. Headphones are also known as earphones or, colloquially, cans.

Headphones are a type of hardware output device that can be connected to a computer's line-out or speakers port, as well as wirelessly using Bluetooth. They are also referred to as earbuds. You can watch a movie or listen to audio without bothering anyone nearby by using headphones.

Summary

A headphone is a small loudspeaker (earphone) held over the ear by a band or wire worn on the head. Headphones are commonly employed in situations in which levels of surrounding noise are high, as in an airplane math, or where a user such as a switchboard operator needs to keep the hands free, or where the listener is moving about or wants to listen without disturbing other people. A headphone may be equipped with one earphone or two and may include a miniature microphone, in which case it is called a headset. For listening to stereophonically reproduced sound, stereo headphones may be used, with separate channels of sound being fed to the two earphones.

An earphone is a small loudspeaker held or worn close to the listener’s ear or within the outer ear. Common forms include the hand-held telephone receiver; the headphone, in which one or two earphones are held in place by a band worn over the head; and the plug earphone, which is inserted in the outer opening of the ear. The conversion of electrical to acoustical signals is effected by any of the devices used in larger loudspeakers; the highest fidelity is provided by the so-called dynamic earphone, which ordinarily is made part of a headphone and equipped with a cushion to isolate the ears from other sound sources.

Details

Headphones are a pair of small loudspeaker drivers worn on or around the head over a user's ears. They are electroacoustic transducers, which convert an electrical signal to a corresponding sound. Headphones let a single user listen to an audio source privately, in contrast to a loudspeaker, which emits sound into the open air for anyone nearby to hear. Headphones are also known as earphones or, colloquially, cans. Circumaural (around the ear) and supra-aural (over the ear) headphones use a band over the top of the head to hold the drivers in place. Another type, known as earbuds or earpieces, consists of individual units that plug into the user's ear canal. A third type are bone conduction headphones, which typically wrap around the back of the head and rest in front of the ear canal, leaving the ear canal open. In the context of telecommunication, a headset is a combination of a headphone and microphone.

Headphones connect to a signal source such as an audio amplifier, radio, CD player, portable media player, mobile phone, video game console, or electronic musical instrument, either directly using a cord, or using wireless technology such as Bluetooth, DECT or FM radio. The first headphones were developed in the late 19th century for use by switchboard operators, to keep their hands free. Initially, the audio quality was mediocre and a step forward was the invention of high fidelity headphones.

Headphones exhibit a range of different audio reproduction quality capabilities. Headsets designed for telephone use typically cannot reproduce sound with the high fidelity of expensive units designed for music listening by audiophiles. Headphones that use cables typically have either a 1/4 inch (6.4 mm) or 1/8 inch (3.2 mm) phone jack for plugging the headphones into the audio source. Some headphones are wireless, using Bluetooth connectivity to receive the audio signal by radio waves from source devices like cellphones and digital players. As a result of the Walkman effect, beginning in the 1980s, headphones started to be used in public places such as sidewalks, grocery stores, and public transit. Headphones are also used by people in various professional contexts, such as audio engineers mixing sound for live concerts or sound recordings and DJs, who use headphones to cue up the next song without the audience hearing, aircraft pilots and call center employees. The latter two types of employees use headphones with an integrated microphone.

History

Headphones grew out of the need to free up a person's hands when operating a telephone. By the 1880s, soon after the invention of the telephone, telephone switchboard operators began to use head apparatuses to mount the telephone receiver. The receiver was mounted on the head by a clamp which held it next to the ear. The head mount freed the switchboard operator's hands, so that they could easily connect the wires of the telephone callers and receivers. The head-mounted telephone receiver in the singular form was called a headphone. These head-mounted phone receivers, unlike modern headphones, only had one earpiece.

By the 1890s a listening device with two earpieces was developed by the British company Electrophone. The device created a listening system through the phone lines that allowed the customer to connect into live feeds of performances at theaters and opera houses across London. Subscribers to the service could listen to the performance through a pair of massive earphones that connected below the chin and were held by a long rod.

French engineer Ernest Mercadier in 1891 patented a set of in-ear headphones. He was awarded U.S. Patent No. 454,138 for "improvements in telephone-receivers...which shall be light enough to be carried while in use on the head of the operator." The German company Siemens Brothers at this time was also selling headpieces for telephone operators which had two earpieces, although placed outside the ear. These headpieces by Siemens Brothers looked fairly similar to modern headphones. The majority of headgear used by telephone operators continued to have only one earpiece.

Modern headphones subsequently evolved out of the emerging field of wireless telegraphy, which was the beginning stage of radio broadcasting. Some early wireless telegraph developers chose to use the telephone receiver's speaker as the detector for the electrical signal of the wireless receiving circuit. By 1902 wireless telegraph innovators, such as Lee de Forest, were using two jointly head-mounted telephone receivers to hear the signal of the receiving circuit. The two head-mounted telephone receivers were called in the singular form "head telephones". By 1908 the headpiece began to be written simply as "head phones", and a year later the compound word "headphones" began to be used.

One of the earliest companies to make headphones for wireless operators was the Holtzer-Cabot Company in 1909. They were also makers of head receivers for telephone operators and normal telephone receivers for the home. Another early manufacturer of headphones was Nathaniel Baldwin. He was the first major supplier of headsets to the U.S. Navy. In 1910 he invented a prototype telephone headset due to his inability to hear sermons during Sunday service. He offered it for testing to the navy, which promptly ordered 100 of them because of their good quality. Wireless Specialty Apparatus Co., in partnership with Baldwin Radio Company, set up a manufacturing facility in Utah to fulfill orders.

These early headphones used moving iron drivers, with either single-ended or balanced armatures. The common single-ended type used voice coils wound around the poles of a permanent magnet, which were positioned close to a flexible steel diaphragm. The audio current through the coils varied the magnetic field of the magnet, exerting a varying force on the diaphragm, causing it to vibrate, creating sound waves. The requirement for high sensitivity meant that no damping was used, so the frequency response of the diaphragm had large peaks due to resonance, resulting in poor sound quality. These early models lacked padding, and were often uncomfortable to wear for long periods. Their impedance varied; headphones used in telegraph and telephone work had an impedance of 75 ohms. Those used with early wireless radio had more turns of finer wire to increase sensitivity. Impedance of 1,000 to 2,000 ohms was common, which suited both crystal sets and triode receivers. Some very sensitive headphones, such as those manufactured by Brandes around 1919, were commonly used for early radio work.

In early powered radios, the headphone was part of the vacuum tube's plate circuit and carried dangerous voltages. It was normally connected directly to the positive high voltage battery terminal, and the other battery terminal was securely grounded. The use of bare electrical connections meant that users could be shocked if they touched the bare headphone connections while adjusting an uncomfortable headset.

In 1958, John C. Koss, an audiophile and jazz musician from Milwaukee, produced the first stereo headphones.

Smaller earbud type earpieces, which plugged into the user's ear canal, were first developed for hearing aids. They became widely used with transistor radios, which commercially appeared in 1954 with the introduction of the Regency TR-1. The most popular audio device in history, the transistor radio changed listening habits, allowing people to listen to radio anywhere. The earbud uses either a moving iron driver or a piezoelectric crystal to produce sound. The 3.5 mm radio and phone connector, which is the most commonly used in portable application today, has been used at least since the Sony EFM-117J transistor radio, which was released in 1964. Its popularity was reinforced with its use on the Walkman portable tape player in 1979.

Applications

Headphones may be used with stationary CD and DVD players, home theater, personal computers, or portable devices (e.g., digital audio player/MP3 player, mobile phone), as long as these devices are equipped with a headphone jack. Cordless headphones are not connected to their source by a cable. Instead, they receive a radio or infrared signal encoded using a radio or infrared transmission link, such as FM, Bluetooth or Wi-Fi. These are battery-powered receiver systems, of which the headphone is only a component. Cordless headphones are used with events such as a Silent disco or Silent Gig.

In the professional audio sector, headphones are used in live situations by disc jockeys with a DJ mixer, and sound engineers for monitoring signal sources. In radio studios, DJs use a pair of headphones when talking to the microphone while the speakers are turned off to eliminate acoustic feedback while monitoring their own voice. In studio recordings, musicians and singers use headphones to play or sing along to a backing track or band. In military applications, audio signals of many varieties are monitored using headphones.

Wired headphones are attached to an audio source by a cable. The most common connectors are 6.35 mm (1/4 inch) and 3.5 mm phone connectors. The larger 6.35 mm connector is more common on fixed location home or professional equipment. The 3.5 mm connector remains the most widely used connector for portable application today. Adapters are available for converting between 6.35 mm and 3.5 mm devices.

As active component, wireless headphones tend to be costlier due to the necessity for internal hardware such as a battery, a charging controller, a speaker driver, and a wireless transceiver, whereas wired headphones are a passive component, outsourcing speaker driving to the audio source.

Some headphone cords are equipped with a serial potentiometer for volume control.

Wired headphones may be equipped with a non-detachable cable or a detachable auxiliary male-to-male plug, as well as some with two ports to allow connecting another wired headphone in a parallel circuit, which splits the audio signal to share with another participant, but can also be used to hear audio from two inputs simultaneously. An external audio splitter can retrofit this ability.

Applications for audiometric testing

Various types of specially designed headphones or earphones are also used to evaluate the status of the auditory system in the field of audiology for establishing hearing thresholds, medically diagnosing hearing loss, identifying other hearing related disease, and monitoring hearing status in occupational hearing conservation programs. Specific models of headphones have been adopted as the standard due to the ease of calibration and ability to compare results between testing facilities.

Supra-aural style headphones are historically the most commonly used in audiology as they are the easiest to calibrate and were considered the standard for many years. Commonly used models are the Telephonics Dynamic Headphone (TDH) 39, TDH-49, and TDH-50. In-the-ear or insert style earphones are used more commonly today as they provide higher levels of interaural attenuation, introduce less variability when testing 6,000 and 8,000 Hz, and avoid testing issues resulting from collapsed ear canals. A commonly used model of insert earphone is the Etymotic Research ER-3A. Circum-aural earphones are also used to establish hearing thresholds in the extended high frequency range (8,000 Hz to 20,000 kHz). Along with Etymotic Research ER-2A insert earphones, the Sennheiser HDA300 and Koss HV/1A circum-aural earphones are the only models that have reference equivalent threshold sound pressure level values for the extended high frequency range as described by ANSI standards.

Audiometers and headphones must be calibrated together. During the calibration process, the output signal from the audiometer to the headphones is measured with a sound level meter to ensure that the signal is accurate to the reading on the audiometer for sound pressure level and frequency. Calibration is done with the earphones in an acoustic coupler that is intended to mimic the transfer function of the outer ear. Because specific headphones are used in the initial audiometer calibration process, they cannot be replaced with any other set of headphones, even from the same make and model.

2304) Stainless Steel

Gist

Stainless steel is a corrosion-resistant alloy of iron, chromium and, in some cases, nickel and other metals. Completely and infinitely recyclable, stainless steel is the “green material” par excellence.

Stainless steel is the name of a family of iron-based alloys known for their corrosion and heat resistance. One of the main characteristics of stainless steel is its minimum chromium content of 10.5%, which gives it its superior resistance to corrosion in comparison to other types of steels.

Summary

Stainless steels are a family of ferrous alloys containing less than 1.2% carbon and over 10.5% chromium and are protected by a passive surface layer of chromium and iron oxides and hydroxides that protects them efficiently from corrosion.

Stainless steel is a family of alloy steels containing low carbon steel with a minimum chromium content of 10% or more by weight. The name originates from the fact that stainless steel does not stain, corrode or rust as easily as ordinary steel; however, ‘stain-less’ is not ‘stain-proof’ in all conditions. It is important to select the correct type and grade of stainless steel for a particular application. In many cases, manufacturing rooms, processing lines, equipment and machines will be subject to requirements from authorities, manufacturers or customers.

The addition of chromium gives the steel its unique stainless, corrosion-resistant properties. The chromium, when in contact with oxygen, forms a natural barrier of adherent chromium(III) oxide (Cr2O3), commonly called ‘ceramic,’ which is a ‘passive film’ resistant to further oxidation or rusting. This event is called passivation and is seen in other metals, such as aluminum and silver, but unlike in these metals this passive film is transparent on stainless steel. This invisible, self repairing and relatively inert film is only a few microns thick so the metal stays shiny. If damaged mechanically or chemically, the film is self-healing, meaning the layer quickly reforms, providing that oxygen is present, even if in very small amounts. This protective oxide or ceramic coating is common to most corrosion resistant materials. Similarly, anodizing is an electrolytic passivation process used to increase the thickness of the natural oxide layer on the surface of metals such as aluminum, titanium, and zinc among others. Passivation is not a useful treatment for iron or carbon steel because these metals exfoliate when oxidized, i.e. the iron(III) oxide (rust) flakes off, constantly exposing the underlying metal to corrosion.

The corrosion resistance and other useful properties of stainless steel can be enhanced by increasing the chromium content and the addition of other alloying elements such as molybdenum, nickel and nitrogen. There are more than 60 grades of stainless steel, however, the entire group can be divided into five classes (cast stainless steels, in general, are similar to the equivalent wrought alloys). Each is identified by the alloying elements which affect their microstructure and for which each is named.

Details

Stainless steel, also known as inox, corrosion-resistant steel (CRES), and rustless steel, is an alloy of iron that is resistant to rusting and corrosion. It contains iron with chromium and other elements such as molybdenum, carbon, nickel and nitrogen depending on its specific use and cost. Stainless steel's resistance to corrosion results from the 10.5%, or more, chromium content which forms a passive film that can protect the material and self-heal in the presence of oxygen.

The alloy's properties, such as luster and resistance to corrosion, are useful in many applications. Stainless steel can be rolled into sheets, plates, bars, wire, and tubing. These can be used in cookware, cutlery, surgical instruments, major appliances, vehicles, construction material in large buildings, industrial equipment (e.g., in paper mills, chemical plants, water treatment), and storage tanks and tankers for chemicals and food products. Some grades are also suitable for forging and casting.

The biological cleanability of stainless steel is superior to both aluminium and copper, and comparable to glass. Its cleanability, strength, and corrosion resistance have prompted the use of stainless steel in pharmaceutical and food processing plants.

Different types of stainless steel are labeled with an AISI three-digit number. The ISO 15510 standard lists the chemical compositions of stainless steels of the specifications in existing ISO, ASTM, EN, JIS, and GB standards in a useful interchange table.

Properties:

Corrosion resistance

Although stainless steel does rust, this only affects the outer few layers of atoms, its chromium content shielding deeper layers from oxidation.

The addition of nitrogen also improves resistance to pitting corrosion and increases mechanical strength. Thus, there are numerous grades of stainless steel with varying chromium and molybdenum contents to suit the environment the alloy must endure. Corrosion resistance can be increased further by the following means:

* increasing chromium content to more than 11%
* adding nickel to at least 8%
* adding molybdenum (which also improves resistance to pitting corrosion)

Strength

The most common type of stainless steel, 304, has a tensile yield strength around 210 MPa (30,000 psi) in the annealed condition. It can be strengthened by cold working to a strength of 1,050 MPa (153,000 psi) in the full-hard condition.

The strongest commonly available stainless steels are precipitation hardening alloys such as 17-4 PH and Custom 465. These can be heat treated to have tensile yield strengths up to 1,730 MPa (251,000 psi).

Melting point

Stainless steel is a steel, and as such its melting point is near that of ordinary steel, and much higher than the melting points of aluminium or copper. As with most alloys, the melting point of stainless steel is expressed in the form of a range of temperatures, and not a single temperature. This temperature range goes from 1,400 to 1,530 °C (2,550 to 2,790 °F; 1,670 to 1,800 K; 3,010 to 3,250 °R) depending on the specific consistency of the alloy in question.

Conductivity

Like steel, stainless steels are relatively poor conductors of electricity, with significantly lower electrical conductivities than copper. In particular, the non-electrical contact resistance (ECR) of stainless steel arises as a result of the dense protective oxide layer and limits its functionality in applications as electrical connectors. Copper alloys and nickel-coated connectors tend to exhibit lower ECR values and are preferred materials for such applications. Nevertheless, stainless steel connectors are employed in situations where ECR poses a lower design criteria and corrosion resistance is required, for example in high temperatures and oxidizing environments.

Magnetism

Martensitic, duplex and ferritic stainless steels are magnetic, while austenitic stainless steel is usually non-magnetic. Ferritic steel owes its magnetism to its body-centered cubic crystal structure, in which iron atoms are arranged in cubes (with one iron atom at each corner) and an additional iron atom in the center. This central iron atom is responsible for ferritic steel's magnetic properties. This arrangement also limits the amount of carbon the steel can absorb to around 0.025%. Grades with low coercive field have been developed for electro-valves used in household appliances and for injection systems in internal combustion engines. Some applications require non-magnetic materials, such as magnetic resonance imaging. Austenitic stainless steels, which are usually non-magnetic, can be made slightly magnetic through work hardening. Sometimes, if austenitic steel is bent or cut, magnetism occurs along the edge of the stainless steel because the crystal structure rearranges itself.

Wear

Galling, sometimes called cold welding, is a form of severe adhesive wear, which can occur when two metal surfaces are in relative motion to each other and under heavy pressure. Austenitic stainless steel fasteners are particularly susceptible to thread galling, though other alloys that self-generate a protective oxide surface film, such as aluminum and titanium, are also susceptible. Under high contact-force sliding, this oxide can be deformed, broken, and removed from parts of the component, exposing the bare reactive metal. When the two surfaces are of the same material, these exposed surfaces can easily fuse. Separation of the two surfaces can result in surface tearing and even complete seizure of metal components or fasteners. Galling can be mitigated by the use of dissimilar materials (bronze against stainless steel) or using different stainless steels (martensitic against austenitic). Additionally, threaded joints may be lubricated to provide a film between the two parts and prevent galling. Nitronic 60, made by selective alloying with manganese, silicon, and nitrogen, has demonstrated a reduced tendency to gall.

Density

The density of stainless steel ranges from 7.5 to 8.0 g/{cm}^3 (0.27 to 0.29 lb/cu in) depending on the alloy.

Additional Information

Stainless steel is any one of a family of alloy steels usually containing 10 to 30 percent chromium. In conjunction with low carbon content, chromium imparts remarkable resistance to corrosion and heat. Other elements, such as nickel, molybdenum, titanium, aluminum, niobium, copper, nitrogen, sulfur, phosphorus, or selenium, may be added to increase corrosion resistance to specific environments, enhance oxidation resistance, and impart special characteristics.

Most stainless steels are first melted in electric-arc or basic oxygen furnaces and subsequently refined in another steelmaking vessel, mainly to lower the carbon content. In the argon-oxygen decarburization process, a mixture of oxygen and argon gas is injected into the liquid steel. By varying the ratio of oxygen and argon, it is possible to remove carbon to controlled levels by oxidizing it to carbon monoxide without also oxidizing and losing expensive chromium. Thus, cheaper raw materials, such as high-carbon ferrochromium, may be used in the initial melting operation.

There are more than 100 grades of stainless steel. The majority are classified into five major groups in the family of stainless steels: austenitic, ferritic, martensitic, duplex, and precipitation-hardening. Austenitic steels, which contain 16 to 26 percent chromium and up to 35 percent nickel, usually have the highest corrosion resistance. They are not hardenable by heat treatment and are nonmagnetic. The most common type is the 18/8, or 304, grade, which contains 18 percent chromium and 8 percent nickel. Typical applications include aircraft and the dairy and food-processing industries. Standard ferritic steels contain 10.5 to 27 percent chromium and are nickel-free; because of their low carbon content (less than 0.2 percent), they are not hardenable by heat treatment and have less critical anticorrosion applications, such as architectural and auto trim. Martensitic steels typically contain 11.5 to 18 percent chromium and up to 1.2 percent carbon with nickel sometimes added. They are hardenable by heat treatment, have modest corrosion resistance, and are employed in cutlery, surgical instruments, wrenches, and turbines. Duplex stainless steels are a combination of austenitic and ferritic stainless steels in equal amounts; they contain 21 to 27 percent chromium, 1.35 to 8 percent nickel, 0.05 to 3 percent copper, and 0.05 to 5 percent molybdenum. Duplex stainless steels are stronger and more resistant to corrosion than austenitic and ferritic stainless steels, which makes them useful in storage-tank construction, chemical processing, and containers for transporting chemicals. Precipitation-hardening stainless steel is characterized by its strength, which stems from the addition of aluminum, copper, and niobium to the alloy in amounts less than 0.5 percent of the alloy’s total mass. It is comparable to austenitic stainless steel with respect to its corrosion resistance, and it contains 15 to 17.5 percent chromium, 3 to 5 percent nickel, and 3 to 5 percent copper. Precipitation-hardening stainless steel is used in the construction of long shafts.

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